Thermal expansion compensator having an elastic conductive element bonded to two facing surfaces

ABSTRACT

A thermal expansion compensator is provided and includes a first electrode structure having a first surface, a second electrode structure having a second surface facing the first surface and an elastic element bonded to the first and second surfaces and including a conductive element by which the first and second electrode structures electrically and/or thermally communicate, the conductive element having a length that is not substantially longer than a distance between the first and second surfaces.

FEDERAL RESEARCH STATEMENT

This invention was conceived under contract no. 1320783 with theNational Air and Space Administration (NASA) having an effective date ofMar. 11, 2008 and relating to differential growth of elements requiringa thermal-mechanical coupler with a low effective Young's Modulus. Thisinvention is unclassified.

BACKGROUND OF THE INVENTION

The subject matter disclosed herein relates to a high temperaturethermal expansion compensator.

High-temperature thermoelectric materials are generally brittle, theyhave a relatively high Young's Modulus and relatively low allowablestrain. They also exhibit low ultimate tensile strength. Several classesof thermoelectric materials exist with different values for theircoefficients of thermal expansion. When thermoelectric materials fromtwo different classes are combined to form a new thermoelectric couple,then, the difference in their coefficient of thermal expansions requiresthat a compensation device be included within the structural frame ofthe couple to prevent buildup of high stress levels in thethermoelectric couple legs and their potential to fracture.

The required properties for such a compensator include a very loweffective Young's Modulus, they should allow for high elastic strain,they should be compatible with the operating environment and have thecapability to demonstrate metallurgical bonding of the compensator intothe thermoelectric couple's electrodes. There are no known materials, orcombination of materials in the form of gradated structures, which cansatisfy all four criteria for the compensator simultaneously.

BRIEF DESCRIPTION OF THE INVENTION

According to one aspect of the invention, a thermal expansioncompensator is provided and includes a first electrode structure havinga first surface, a second electrode structure having a second surfacefacing the first surface and an elastic element bonded to the first andsecond surfaces and including a conductive element by which the firstand second electrode structures electrically and/or thermallycommunicate, the conductive element having a length that is notsubstantially longer than a distance between the first and secondsurfaces.

According to another aspect of the invention, a thermal expansioncompensator is provided and includes a first electrode structure havinga first surface, a second electrode structure having a second surfacefacing the first surface and a series of coils arranged side-by-side andbetween the first and second electrode structures with respectiveportions of each of the coils metallurgically bonded to correspondingportions of the first and second surfaces.

According to another aspect of the invention, a thermal expansioncompensator is provided and includes a first electrode structure havinga first surface, a second electrode structure having a second surfacefacing the first surface and wiring, including two or more wiresections, each of which is coiled to form a coil section having opposingends corresponding to opposing wire section ends and sides extendingtherebetween, each of the coil sections being disposed sidelong betweenthe first and second electrode structures with respective portions ofeach of the coil section sides metallurgically bonded to correspondingportions of the first and second surfaces.

According to another aspect of the invention, a thermal expansioncompensator is provided and includes a first electrode structure havinga first surface, a second electrode structure having a second surfacefacing the first surface and wiring, including two or more wiresections, each of which is coiled to form a coil section having opposingends corresponding to opposing wire section ends and sides extendingtherebetween, each of the coil sections being disposed between the firstand second electrode structures such that longitudinal axes thereof aresubstantially parallel with respective planes of the first and secondsurfaces with respective portions of each of the coil section sidesmetallurgically bonded to corresponding portions of the first and secondsurfaces.

According to yet another aspect of the invention, a method of assemblinga thermal expansion compensator is provided and includes disposing coilswith pins inserted therein on a first foil layer disposed on a firstelectrode, disposing a second foil layer and then a second electrode onthe pins and the coils, loading and then bonding the coils to the firstand second foils layers and the first and second foil layers to thefirst and second electrodes to form an assembly, removing the pins andcompressing the assembly in a direction perpendicular to a longitudinaldirection of the coils to achieve a coil compression.

These and other advantages and features will become more apparent fromthe following description taken in conjunction with the drawings.

BRIEF DESCRIPTION OF THE DRAWING

The subject matter which is regarded as the invention is particularlypointed out and distinctly claimed in the claims at the conclusion ofthe specification. The foregoing and other features, and advantages ofthe invention are apparent from the following detailed description takenin conjunction with the accompanying drawings in which:

FIG. 1 is a side view of a thermal expansion compensator metallurgicallybonded to electrodes;

FIG. 2 is another side view of the compensator metallurgically bonded toelectrodes; and

FIG. 3A is an axial view of a first pin inserted into a coil; and

FIG. 3B is an axial view of a second pin inserted into the coil of FIG.3A having been compressed.

The detailed description explains embodiments of the invention, togetherwith advantages and features, by way of example with reference to thedrawings.

DETAILED DESCRIPTION OF THE INVENTION

With reference to FIGS. 1 and 2, a thermal expansion compensator 10 isprovided and includes a first electrode structure 11 having a firstsurface 12, a second electrode structure 13 having a second surface 14facing the first surface 12 and an elastic element bonded to the firstand second surfaces 12 and 14. The elastic element includes anelectrically and/or thermally conductive element by which the first andsecond electrode structures 11 and 13 electrically and/or thermallycommunicate with one another along pathways defined by the electricallyand/or thermally conductive element. The electrically and/or thermallyconductive element has a length that is not substantially longer than adistance between the first and second surfaces.

The elastic element may include cushioning resin or epoxy that isconductive or in which the conductive element is suspended, memory foamthat is conductive or in which the conductive element is suspended,coils laid on end, coils laid on their sides as described below, leafsprings or similar types of elastic or cushioning devices. In any case,the pathways along which the first and second electrode structures 11and 13 electrically and/or thermally communicate have respective lengthsthat are equal to or slightly longer than the distance between the firstand second surfaces 12 and 14. That is, if the distance between thefirst and second surfaces 12 and 14 is X, the respective lengths of thepathways may be X to about 2X.

In accordance with embodiments, the thermal expansion compensator 10 isprovided and includes the first electrode structure 11 having the firstsurface 12, the second electrode structure 13 having the second surface14, which faces the first surface 12 and a series of coils 15 arrangedside-by-side and between the first and second electrode structures 11and 13 with respective portions 155 of each of the coils 15metallurgically bonded to corresponding portions 111 and 133 of thefirst and second surfaces 12 and 14.

The coils 15 may be provided in numbers of two or more and may be formedof wiring, including two or more wire sections 20, 21, where each wiresection 20, 21 is coiled into a coil section 25. The coil section 25 hasopposing ends 26, 27 that correspond to opposing wire section ends 28,29 and sides 30 extending between the opposing ends 26, 27. Each of thecoil sections 25 may be disposed sidelong between the first and secondelectrode structures 11 and 13 such that longitudinal axes, A_(L), ofthe coil sections 25 are substantially parallel with planes, P₁ and P₂,of the first and second electrode structures 11 and 13. With the coilsections 25 disposed in this manner, the respective portions 155 of forexample each of the coil section sides 30 are metallurgically bonded tothe corresponding portions 111, 133 of the first and second surfaces 12and 14.

The coils 15 may include helical coiling with, for example, 85 turns per0.285″ or about 300 turns per inch. The coils 15 may be separate fromone another, as shown in FIG. 1 or, in some cases, provided as acontinuous serpentine structure whereby the coils 15 includesubstantially straight portions and, for example, hairpin sections. Inany case, the coils 15 include wires or wiring having a relatively smalldiameter relative to a distance between the first and second electrodestructures 11 and 13.

The first electrode structure 11 includes a base 40 formed of molybdenum(Mo) and, in some cases, stainless steel or similar materials. The firstelectrode 11 further includes a titanium (Ti) layer 41 at the firstsurface 12. Like the base, the coils 15 may be formed of molybdenum. Thesecond electrode structure 13 is arranged similarly with a molybdenumbase 50 and a titanium layer 51. In this way, when the thermal expansioncompensator 10 is assembled, during a bonding process in which thethermal expansion compensator is loaded and heated to about 760 degreesCelsius for about 120 minutes, the molybdenum of the respective bases40, 50 diffusion bonds with the titanium layers 41, 51 of the respectivefirst and second surfaces 12 and 14. Similarly, the titanium layers 41,51 of the respective first and second surfaces 12 and 14 diffusion bondswith the molybdenum of the coils 15 at the respective portions 155.Since the bonding temperature is relatively low as compared to, forexample, the melting temperatures of components associated with thethermal expansion compensator 10, damage to those components during thebonding process can be avoided or substantially reduced.

The thermal expansion compensator 10 described herein thus employs a setof, for example, helical coils 15, made from relatively small diameterwire, which are laid on their sides 30. These coils 15 aremetallurgically bonded into the first and second electrode structures 11and 13. Once the bonding is achieved, the coils 15 act like springs inthe orthogonal direction allowing elastic compression of each wire ringfor a relatively low deflection force. Models of coil diametricaldeflection with applied force can be applied to predict overallforce-deflection behavior and to calculate its effective springconstant. In the thermal expansion compensator 10, therefore softcompliance (i.e., thermal expansion) is possible along with low thermaland electrical impedance. In particular, a relatively very low effectiveYoung's Modulus is achieved under relatively high elastic strain levelsof 15% or greater.

Coil diameter and coil-to-wire outside diameter ratios can be varied inthe design of the thermal expansion compensator 10 to change the desiredelastic deflection range. The number of coils 15, the wire material andits treatment and the number of turns per inch of coil 15 can be changedto adjust the effective spring constant. The wire material can beselected or a twisted wire rope construction can be used for differentoperating environments and other uses.

In accordance with further aspects of the invention, the thermalexpansion compensator 10 is assembled with reference to FIG. 3A.Initially, the coils 15 are formed and positioned onto pins 60, such astemporary molybdenum pins, and held with a holder. The holder, the pins60 and the coils 15 are then positioned on temporary foil for subsequenttransfer. A layer 41 of titanium foil (0.0005″ thick) is then placedonto a molybdenum base 40 of the first (hot) electrode structure 11 andthe holder, the pins 60 and the coils 15 are placed on top of thetitanium layer 41. At this point, positions of the pin 60 and thetitanium layer 41 are verified and a second titanium layer 51 is placedon top of the coils 15. The base 50 of the second electrode structure 13is then placed on the layer 51, a remainder of tooling for applying loadis installed and the structure is transferred to, for example, a furnacehearth where load application may be prepared.

The bonding process includes application of a downward load to the base50 of the second electrode structure 13 and across the coils 15 to bebonded. Bonding is then performed at about 760 degrees Celsius for about120 minutes. Once the bonding is complete, the pins 60 are removed fromthe coils 15 under a microscope as is necessary. Following pin 60removal, the coils 15 may be optionally compressed using tooling toprecisely control a position of the base 50. Thus, the thermal expansioncompensator 10 assembly can be compressed to provide a desiredcompression of the coils 15 perpendicular to their longitudinal axes,A_(L). This compression is optional and may be carried out to modify thecoil shape, as shown in FIG. 3B, and thereby to modify the effectiveYoung's modulus of the assembly.

With reference to FIG. 3B, a second optional bond cycle may be employedto provide for additional bonding beyond that which is achieved in theinitial bonding. Here, a second set of pins 70, such as molybdenum pinsor stainless steel pins, are selected and sized to precisely fit theinner diameter obtained in the coil 15 compression. The second pins 70are installed and provide support during a second loading and bondingsequence, which is substantially similar to the initial sequence.

While the invention has been described in detail in connection with onlya limited number of embodiments, it should be readily understood thatthe invention is not limited to such disclosed embodiments. Rather, theinvention can be modified to incorporate any number of variations,alterations, substitutions or equivalent arrangements not heretoforedescribed, but which are commensurate with the spirit and scope of theinvention. Additionally, while various embodiments of the invention havebeen described, it is to be understood that aspects of the invention mayinclude only some of the described embodiments. Accordingly, theinvention is not to be seen as limited by the foregoing description, butis only limited by the scope of the appended claims.

1. A thermal expansion compensator, comprising: a first electrodestructure having a first surface; a second electrode structure having asecond surface facing the first surface; and an elastic element bondedto the first and second surfaces and including a conductive element bywhich the first and second electrode structures electrically and/orthermally communicate, the conductive element having a length that isnot substantially longer than a distance between the first and secondsurfaces.
 2. A thermal expansion compensator, comprising: a firstelectrode structure having a first surface; a second electrode structurehaving a second surface facing the first surface; and a series of coilsarranged side-by-side and between the first and second electrodestructures with respective portions of each of the coils metallurgicallybonded to corresponding portions of the first and second surfaces. 3.The thermal expansion compensator according to claim 2, wherein thecoils comprise helical coiling.
 4. The thermal expansion compensatoraccording to claim 2, wherein the coils are separate from one another.5. The thermal expansion compensator according to claim 2, wherein thecoils comprise wires having relatively small diameters relative to adistance between the first and second electrode structures.
 6. Thethermal expansion compensator according to claim 2, wherein the firstand second electrode structures comprise molybdenum (Mo).
 7. The thermalexpansion compensator according to claim 6, wherein the first and secondelectrode structures further comprise titanium (Ti).
 8. The thermalexpansion compensator according to claim 7, wherein the coils comprisewiring formed of molybdenum (Mo).
 9. A thermal expansion compensator,comprising: a first electrode structure having a first surface; a secondelectrode structure having a second surface facing the first surface;and wiring, including two or more wire sections, each of which is coiledto form a coil section having opposing ends corresponding to opposingwire section ends and sides extending therebetween, each of the coilsections being disposed sidelong between the first and second electrodestructures with respective portions of each of the coil section sidesmetallurgically bonded to corresponding portions of the first and secondsurfaces.
 10. The thermal expansion compensator according to claim 9,wherein the coil sections comprise helical coiling.
 11. The thermalexpansion compensator according to claim 9, wherein the coil sectionsare separate from one another.
 12. The thermal expansion compensatoraccording to claim 9, wherein the wire sections have a relatively smalldiameter relative to a distance between the first and second electrodestructures.
 13. The thermal expansion compensator according to claim 9,wherein the first and second electrode structures comprise molybdenum(Mo).
 14. The thermal expansion compensator according to claim 13,wherein the first and second electrode structures comprise titanium(Ti).
 15. The thermal expansion compensator according to claim 14,wherein the wiring comprises molybdenum (Mo).
 16. A thermal expansioncompensator, comprising: a first electrode structure having a firstsurface; a second electrode structure having a second surface facing thefirst surface; and wiring, including two or more wire sections, each ofwhich is coiled to form a coil section having opposing endscorresponding to opposing wire section ends and sides extendingtherebetween, each of the coil sections being disposed between the firstand second electrode structures such that longitudinal axes thereof aresubstantially parallel with respective planes of the first and secondsurfaces with respective portions of each of the coil section sidesmetallurgically bonded to corresponding portions of the first and secondsurfaces. 17-22. (canceled)